Aissen–Schoenberg–Whitney
A finite sequence of nonnegative reals is a Pólya frequency sequence if and only if its generating polynomial has only real, nonpositive zeros. Both directions are proved.
References
M. Aissen, I. J. Schoenberg, and A. M. Whitney, “On the generating functions of totally positive sequences. I,” Journal d’Analyse Mathématique 2 (1952), 93–103. See the Pólya-frequency overview on symmetricfunctions.com.